{"id":452030,"date":"2018-03-14T09:23:43","date_gmt":"2018-03-14T13:23:43","guid":{"rendered":"https:\/\/www.sciencedaily.com\/releases\/2018\/03\/180314092343.htm"},"modified":"2018-03-14T09:23:43","modified_gmt":"2018-03-14T13:23:43","slug":"exploration-of-a-new-chemical-synthesis-process-synergy-of-two-catalysts-in-one-flask","status":"publish","type":"post","link":"https:\/\/spaceweekly.com\/?p=452030","title":{"rendered":"Exploration of a new chemical synthesis process &#8212; synergy of two catalysts in one flask"},"content":{"rendered":"<p>Development of a general and simple reaction by an organocatalyst and a transition-metal catalyst in cooperation is highly desirable for various organic syntheses but remains a challenge. Herein, we report the one-step synthesis of a ketone from an aldehyde by the combination of thiazolium N-heterocyclic carbene and palladium\/bisphosphine catalysts in one flask. The two catalysts function in a synergistic manner. This study is expected to lead to new synthesis processes of precursor compounds for medications. <\/p>\n","protected":false},"excerpt":{"rendered":"<p>Development of a general and simple reaction by an organocatalyst and a transition-metal catalyst in cooperation is highly desirable for various organic syntheses but remains a challenge. Herein, we report the one-step synthesis of a ketone from an ald&#8230;<\/p>\n","protected":false},"author":61,"featured_media":615444,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[],"tags":[],"class_list":["post-452030","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry"],"_links":{"self":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts\/452030","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/users\/61"}],"replies":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=452030"}],"version-history":[{"count":1,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts\/452030\/revisions"}],"predecessor-version":[{"id":452031,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts\/452030\/revisions\/452031"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/media\/615444"}],"wp:attachment":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=452030"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=452030"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=452030"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}