{"id":542028,"date":"2018-11-02T09:55:07","date_gmt":"2018-11-02T13:55:07","guid":{"rendered":"https:\/\/www.sciencedaily.com\/releases\/2018\/11\/181102095507.htm"},"modified":"2018-11-02T09:55:07","modified_gmt":"2018-11-02T13:55:07","slug":"alcohols-as-carbon-radical-precursors","status":"publish","type":"post","link":"https:\/\/spaceweekly.com\/?p=542028","title":{"rendered":"Alcohols as carbon radical precursors"},"content":{"rendered":"<p>Carbon radicals are attractive intermediates for organic synthesis because of their diversity and high reactivities. In this research, we realized radical C-C bond formation reactions using alcohols as straightforward carbon radical precursors. We used a newly developed low-valent titanium reagent to cleave the C-O bonds of benzyl alcohol derivatives to generate the corresponding carbon radicals. This method was successfully applied to radical coupling reactions with several electron-deficient alkenes. <\/p>\n","protected":false},"excerpt":{"rendered":"<p>Carbon radicals are attractive intermediates for organic synthesis because of their diversity and high reactivities. In this research, we realized radical C-C bond formation reactions using alcohols as straightforward carbon radical precursors. We used&#8230;<\/p>\n","protected":false},"author":61,"featured_media":615444,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[],"tags":[],"class_list":["post-542028","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry"],"_links":{"self":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts\/542028","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/users\/61"}],"replies":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=542028"}],"version-history":[{"count":1,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts\/542028\/revisions"}],"predecessor-version":[{"id":542029,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts\/542028\/revisions\/542029"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/media\/615444"}],"wp:attachment":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=542028"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=542028"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=542028"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}