{"id":671463,"date":"2020-10-29T13:13:31","date_gmt":"2020-10-29T17:13:31","guid":{"rendered":"http:\/\/spaceweekly.com\/?p=671463"},"modified":"2020-10-29T13:13:31","modified_gmt":"2020-10-29T17:13:31","slug":"visible-light-induced-bifunctional-rhodium-catalysis-developed-for-decarbonylative-coupling-of-imides-with-alkynes","status":"publish","type":"post","link":"https:\/\/spaceweekly.com\/?p=671463","title":{"rendered":"Visible light-induced bifunctional rhodium catalysis developed for decarbonylative coupling of imides with alkynes"},"content":{"rendered":"<p>Carbonyl groups are ubiquitous in pharmaceuticals, natural products, and agricultural chemicals, especially amides. Transition metal-catalyzed decarbonylation offers a distinct synthetic strategy for new chemical bond formation and carbonyl groups transformation. However, the \u03c0-backbonding between CO \u03c0* orbitals and metal center d-orbitals impedes ligand dissociation to regenerate catalyst under mild condition.&#013;<br \/>\n&#013;<br \/>\n&#013;<br \/>\n Click here for original story, <a href=\"https:\/\/phys.org\/news\/2020-10-visible-light-induced-bifunctional-rhodium-catalysis.html\" target=\"_blank\" rel=\"nofollow noopener noreferrer\">Visible light-induced bifunctional rhodium catalysis developed for decarbonylative coupling of imides with alkynes<\/a>&#013;<br \/>\n&#013;<br \/>\n&#013;<br \/>\nSource: Phys.org&#013;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Carbonyl groups are ubiquitous in pharmaceuticals, natural products, and agricultural chemicals, especially amides. Transition metal-catalyzed decarbonylation offers a distinct synthetic strategy for new chemical bond formation and carbonyl groups transformation.&hellip; <\/p>\n","protected":false},"author":1,"featured_media":615444,"comment_status":"false","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[41],"tags":[],"class_list":["post-671463","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-phys-org"],"_links":{"self":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts\/671463","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=671463"}],"version-history":[{"count":0,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts\/671463\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/media\/615444"}],"wp:attachment":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=671463"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=671463"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=671463"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}