{"id":760086,"date":"2023-07-10T10:27:04","date_gmt":"2023-07-10T14:27:04","guid":{"rendered":"http:\/\/spaceweekly.com\/?p=760086"},"modified":"2023-07-10T10:27:04","modified_gmt":"2023-07-10T14:27:04","slug":"ni-ti-bimetallic-system-mediates-enantioselective-reductive-aryl-benzylation-of-alkenes-using-free-alcohols","status":"publish","type":"post","link":"https:\/\/spaceweekly.com\/?p=760086","title":{"rendered":"Ni-Ti bimetallic system mediates enantioselective reductive aryl-benzylation of alkenes using free alcohols"},"content":{"rendered":"<p>Prof. Wang Xiaoming&#8217;s group at the Shanghai Institute of Organic Chemistry, of the Chinese Academy of Sciences, has demonstrated the first nickel-titanium, bimetallic, system-catalyzed, asymmetric reductive aryl-benzylation of alkenes using benzyl alcohols, which afforded a series of biologically important benzene-fused cyclic compounds in good yields with high enantiomeric excess (ee) values. The work was published in Cell Reports Physical Science.&#013;<br \/>\n&#013;<br \/>\n&#013;<br \/>\n Click here for original story, <a href=\"https:\/\/phys.org\/news\/2023-07-ni-ti-bimetallic-enantioselective-reductive-aryl-benzylation.html\" target=\"_blank\" rel=\"nofollow noopener\">Ni-Ti bimetallic system mediates enantioselective reductive aryl-benzylation of alkenes using free alcohols<\/a>&#013;<br \/>\n&#013;<br \/>\n&#013;<br \/>\nSource: Phys.org&#013;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Prof. Wang Xiaoming&#8217;s group at the Shanghai Institute of Organic Chemistry, of the Chinese Academy of Sciences, has demonstrated the first nickel-titanium, bimetallic, system-catalyzed, asymmetric reductive aryl-benzylation of alkenes using&hellip; <\/p>\n","protected":false},"author":1,"featured_media":615444,"comment_status":"false","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[41],"tags":[],"class_list":["post-760086","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-phys-org"],"_links":{"self":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts\/760086","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=760086"}],"version-history":[{"count":0,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/posts\/760086\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=\/wp\/v2\/media\/615444"}],"wp:attachment":[{"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=760086"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=760086"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/spaceweekly.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=760086"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}