Atoms are the basic building blocks of all matter—at least, that is the conventional picture. In a new study, researchers have fabricated the first superatomic 2-D semiconductor, a material whose basic units aren’t atoms but superatoms—atomic clusters that exhibit some of the properties of one or more individual atoms. The researchers expect that the new material is just the first member of what will become a new family of 2-D semiconductors whose superatomic structures will greatly expand the diversity, functionality, and applications of 2-D materials.