Abstract: The X(exp 1)Sigma(+) state of MgO shows significant differences between the CCSD(T) and CCSDT results and even some significant differences between the CCSDT and CCSDTQ results. The CCSDT(Q) results for this state do not agree well with the CCSDTQ results, as has been found for other systems. Unlike the X state, the state, which is well described by a single configuration, shows much less dependence on level of correlation treatment. Despite the slow convergence of the valence treatment of th…