Nanoparticle superlattice films that form at the solid-liquid interface are important for mesoscale materials but are challenging to analyze on the onset of formation at a solid-liquid interface. In a new report on Science Advances, E. Cepeda-Perez and a research team in materials, physics and chemistry in Germany studied the early stages of nanoparticle assembly at solid-liquid interfaces using liquid-phase electron microscopy. They observed oleylamine-stabilized gold nanoparticles to spontaneously form thin layers on a silicon nitride membrane window of the liquid enclosure. In the first monolayer, the assembly maintained dense packings of hexagonal symmetry independent of the nonpolar solvent type. The second layer displayed geometries ranging from dense packing in a hexagonal honeycomb structure to quasi-crystalline particle arrangements—based on the dielectric constant of the liquid. The complex structures made of weaker interactions remained preserved, while the surface remained immersed in liquid. By fine-tuning the properties of materials involved in nanoparticle superlattice formation, Cepeda-Perez et al. controlled the three-dimensional (3-D) geometry of a superlattice, including quasi-crystals (a new state of matter).
Click here for original story, Electron microscopy of nanoparticle superlattice formation at a solid-liquid interface in non-polar liquids
Source: Phys.org