Flip through any chemistry textbook and you’ll see drawings of the chemical structure of molecules—where individual atoms are arranged in space and how they’re chemically bonded to each other. For decades, chemists could only indirectly determine chemical structures based on the response generated when samples interacted with x-rays or particles of light. For the special case of molecules on a surface, atomic force microscopy (AFM), invented in the 1980s, provided direct images of molecules and the patterns they form when assembling into two-dimensional (2D) arrays. In 2009, significant advances in high-resolution AFM (HR-AFM) allowed chemists for the first time to directly image the chemical structure of a single molecule with sufficient detail to distinguish different types of bonding inside the molecule.
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Source: Phys.org