Photoelectrodes based on BiVO4 are considered top candidates for solar hydrogen production. But what exactly happens when they come into contact with water molecules? A study in the Journal of the American Chemical Society has now partially answered this crucial question: Excess electrons from dopants or defects aid the dissociation of water which in turn stabilizes so-called polarons at the surface. This is shown by data from experiments conducted at the Advanced Light Source at Lawrence Berkeley National Laboratory. These insights might foster a knowledge-based design of better photoanodes for green hydrogen production.
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Source: Phys.org