Electrochemical water splitting is favorable strategy to produce high-purity H2. The current mainstream catalysts for water electrolysis are precious metals (Pt, RuO2, IrO2), which possess superior catalytic activity, relatively low over-potential and favorable catalytic kinetics, but their high cost and poor cycle stability is still unaffordable. Therefore, researchers seek a new type of hydrogen production catalyst with low cost, high catalytic activity and high stability.